adds enchantments that give the respective item a chance to drop a rare item when used
Weapon enchant that has a 1 in 100,000 to drop a Golden Rotten Flesh when killing entities.
Hoe enchant that has a 1 in 100,000 to drop a Golden Potato when breaking bonemealable blocks.
Nothing, they are simply a trophy to the fact you got such a rare drop.
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